Discussion Board 3-1 Assignment Example | Topics and Well Written Essays - 250 words - 6

Discussion Board 3-1 - Assignment Example To simplify his reasons for Systems Theory, Bowen introduced the use of genogram in analyzing and understanding family processes and issues. Genogram is a schematic diagram or structure for mapping family relationships, patterns, and processes across at least three consecutive generations. Nichols (2013) elaborates that the structure details marriage relationships, dates of births, dates of death, geographical locations and general relationships of family members in different times within the covered generations. Just like other techniques of treating psychological and family disorders, genograms have their advantages and disadvantages. The main advantage of a genogram is that its structure provides family therapist with detailed information about a family in treatment. A genogram uses clear symbols, shapes and lines to show various relationships, identify individuals, and disclose events. As demonstrated by Nichols (2013), the diagram also shows dates when certain events happened across the covered generations of a given family. With such information, a family therapist is able to trace and glean elaborate understanding of dynamics that lead a family to its contemporary condition. To this extent, therapists can device reliable if not very accurate treatment techniques and processes. Another advantage of genogram is that it enables members of embattled family trace and understands the source(s) of their problem(s). The fact that genograms cover events that transpired across at least three generations of a family enables family members to gain proper self-knowledge, understand consequences of their actions and hypothesize ways to restructure their lives and behaviors (Nichols, 2013). The greatest disadvantage of genogram over talking with family members about their immediate concerns relates to likelihood to consume a lot of time. The act of tracing historical events of a family down across at least three generation is time consuming (Nichols, 2013).

The Neuropsychological Double Dissociation Psychology Essay

The Neuropsychological Double Dissociation Psychology Essay Uncomfortable bedfellows; according to Bishop this constitutes the relationship between cognitive neuropsychology and developmental disorders. Boyle et al. (2011) showed that one out of six children suffer from a developmental disorder. The ICD-10 (WHO, 1992) defines developmental disorders (DD) as fulfilling three categories: an early onset, a delay in developmental functions relating to the CNS or biological maturation and a lack of remission. The DSM-IV (APA, 2000) takes a different direction by categorising Pervasive Developmental Disorders as characterized by impaired development of reciprocal social interaction and communication skills and the presence of stereotyped behaviour, interests, and activities. Whilst the first definition describes DD like developmental Prosopagnosia (face blindness, DP) which affects around 2.47% of the population (Kennerknecht, Grueter T., Welling, Wentzek, Horst, Edwards, Grueter M., 2006), the latter definition matches the triad of impairments of autism (ASD) which has a prevalence of 1% (Boyle et al., 2011). Comorbidity of DD such as ASD and prosopagnosia can result (Bate, 2012). At the same time, around 20% of individuals over 18 years suffer from acquired brain disorders and diseases (Family Caregiver Alliance, 2012). Deficits in acquired and developmental individuals are commonly mapped out using functional models and explored via double-dissociations. These are usually derived from acquired disorder (AD) patients rather than DD patients. How these factors influence the debate of cognitive neuropsychology and DD making uncomfortable bedfellows shall be explored in the following. Several points will be discussed as having an influential role in the debate of cognitive neuropsychology (CN) accounting for developmental disorders (DD). These are: modularity, plasticity and compensation, competence and performance, differences between exploring AD and DD and the role of double-dissociations in relation to developmental versus acquired disorders as displayed in CN. The association between structural and cognitive development is gaining recognition. Developmental changes in task-specific processing such as that of faces have been argued to play an important role in the amalgamation of various brain networks and experience-based growth of neural architecture (Westermann, Sirois, Shultz, Mareschal, 2006). Also, a bidirectional interaction between behavioural and neuronal development has been established as learning supposedly influences brain structuring and vice versa. Similarly, the rate of neurogenesis arguably depends on learning and environmental circumstances (Westermann et al., 2006). (Bishop, 1997, p.902) Following on from that, cognition is executed by the growing neurofunctional network. This distributed parallel processing arguably is organised into interacting modules (Table 1), which comprise of different levels of complexity depending on the cognitive task or function carried out (Jackson, 1958). This can be illustrated by Theory of Mind (Baron-Cohen, 1995) in ASD: ToM proposes developmental impairment of the ability to appreciate own and others mental states (beliefs, desires or intentions etc). Adams (2010), Brothers (1990) theory of the Social Brain and Leslies (1991) ToM Mechanism argue that key features of ToM can be explained in terms of modularity. Marchery (forthcoming) supports this as modularity poses a crucial characteristic of biological development. Arguably, deficits are not due to minor developmental brain problems in lower-level input and consequential cascading abnormal interaction between input and higher-level systems that affect all cognitive capacities (Karmiloff-Smith, 1998; 1992; Machery, forthcoming). Nonetheless, this is what Gerrans P.,T. and Stone (2008) argue. Additionally, low-level deficits such as gaze and face processing prevent ASD individuals from having the same experience as typically developing individuals, caused by a deficit in domain-general capacity. This has the aforementioned cascading interaction effect during development rather than leading to a dysfunctional mindreading module. However, Gerrans et al. do not see development as single causality. Reconciling, Baron-Cohen (1995) postulates that ToM is either seen as innate module or explained by deficits in general learning mechanisms and unifies both in the intermediate model of Social Perception of Minimalist Innate Modularity. (Amaral, Schumann, Nordahl, 2008, p.2) Figure 1 displays brain structures associated with dysfunctions in ASD. Amaral et al. (2008) join the debate of modularity suggesting that despite functional identification of modules no clear pathology has emerged yet but rather, that e.g. Schumann and Amaral, (2004) have demonstrated that the developmental trajectory itself rather than the final product exhibits most disruption and by this posing a further point against applying CN to the explanation of DD. Functions of modularity imply, on the other hand, that one zone can belong to several overlapping neuronal networks (Damasceno, 2010).Disordered brain development can lead to structural disruption and thereby to several dysfunctions which may not appear as a specific deficit but as a syndrome (a collection of symptoms) as demonstrated in the triad of impairments in ASD (Wing Gould, 1979). Similarly, lesions to a localised brain area do not always cause isolated but sometimes collective symptoms (Kolb, Brown, Witt-Lajeunesse, Gibb, 2001). These are caused, i.a. by disturbances in interconnected regions which might appear intact on functional brain imaging scans. However, changes in neurotransmission, excitatory or inhibitory processes or blood flow might cause secondary symptoms not predicted by the data. One interesting example was proposed by Sandel, Weiss and Ivker (1990): their patient was described as amnesic after traumatic brain injury. Her impaired cognition was considered a secondary deficit as her EEG and other clinical tests proved negative. No other disruptions were present until she was eventually diagnosed with multiple personality disorder. Therefore several unexpected and seemingly unconnected functional disruptions might result from a single localised lesion. These points argue against the notion of using CN in explaining DD due to the assumptions held. Advancing to the next argument, functional (mal)development following lesions or disrupted neurogenesis might also demonstrate individual differences in brain structure, due to varying input, demands and circumstances. Thomas and Karmiloff-Smith (2003) added that specialisation/modularity is not directing development but contrarily, is the outcome of this. On the other hand, the brain activity of healthy individuals supports a normalisation process to facilitate models being created for generalisation purposes. As Tager-Flusberg (1999) counter-argues, functional variation in dysfunctional individuals is similar to that of typical population. Allegedly, localisation is universally alike thereby plasticity, compensation or adaptation to damage are neglected. Examples of compensatory processes and resulting behaviour (or v.v.?) are stimming in ASD for sensory overload (Grandin, 2009) or remembering haircuts in prosopagnosics for identification (Bate, 2012). Adaptation can express itself by change in neurochemistry, psychomotor stimulants and compensatory behaviour while it is argued that the behaviour triggers alteration in neurochemistry (Kolb et al., 2001). This in turn, points to the aforementioned bidirectionality of structure and learning which has implications for acquired as well as developmental patients and goes against explaining DD in a CN framework. At this point, double-dissociations are commonly applied to provide clues to brain-behaviour relationships. In 1955, Teuber introduced the term double-dissociation referring to mirror-deficit patients. Buchaine, Parker, and Nakayama (2003) proposed the example of NM, a prosopagnosic whose abilities support previous findings (Young, Newcombe, De Haan, Small, Hay, 1993) of a double-dissociation of identity and emotion recognition. Van Peelen, Lucas, Mayer, and Vuilleumier (2009) added that emotional guidance of attention to facial expression can be unimpaired and thus functionally differ from face identification. Interestingly, Teuber did not establish double-dissociations to discover networks within cognitive architecture (Van Orden, Pennington, Stone, 2001) as localising a lesion does not imply a responsibility for dysfunctions. Further, modularity of functional networks has not been unanimously established. Nonetheless, modularity is one key feature of CN serving the notion of double-dissociations. CN informs theories of normal cognitive function by analysing the break down of cognitive systems in atypical patients (Bullinaria Chater, 1997). However, inferring theory from damage patients is full of obstacles and depends on models of normal functioning. As Caramazza (1984) argued, double-dissociations are valid forms of inference but only if the cognitive model is well developed; only single-case studies can provide information relevant to our understanding of cognitive architecture. Contradicting, Shallice (1988) argued that a double-dissociation between two tasks does not necessarily imply a double-dissociation between cognitive processes. Since the argument concerning emergence of CN models and the role of AD and DD has not been resolved yet, a need of inclusion of further aspects becomes apparent. One aspect is Residual Normality which claims that atypical development impairs only specific domains while the rest functions typically (Thomas Karmiloff-Smith, 2002). Similar behavioural impairments demonstrated by adult brain damage and infant-onset disorders are assumed to support modularity of typical neuronal system structure. Opposing the assumption of RN, compensation due to damage causes alterations in various other modules (Thomas, 2003). Shallice (1988) introduced deriving knowledge about the neuronal system from behavioural impairments in AD and DD, such as malfunctioning ToM in autism (Leslie, 1991). As argued by Bishop and Karmiloff-Smith (1997; 1998) such an inferential process within the static model of CN leads to invalid explanations of dysfunctional development. Functional Models on the other hand do not possess a developmental component, and display what is expected to happen under various conditions in terms of functionality and processes (DMello Franklin, 2011). Thus impairments can be analysed under the assumption of RN as it has been done, for example in the study of autism and prosopagnosia (Thomas et al., 2002). Examples of models are given in Figure two and three. Despite this, it has been suggested to use connectionist models where in AD the damage is applied at the end of training and for DD prior to it as this is argued to reflect actuality in a truer light. Connectionist models indeed are suitable for the investigation of DD as behavioural deficits such as in autism (Thomas et al., 2002) can be captured well following simulated atypical development. It is highlighted that AD and DD are studied using separate models, thereby arguing against functional models within CN. Figure 2: Functional model of face-processing (Wright, Wardlaw, Young, Zeman, 2006) Figure 3: Models of Autism (Anderson and Herbert, 2008) The aforementioned factors influencing whether cognitive neuropsychology is suitable for explaining DD have given a mixed picture. Jackson and Coltheart (2001) defended the use of CN in DD stating that development itself (thus distal causes like genes or background) are irrelevant for the identification of un/healthy functions, given modularity. Whether acquired or developmental proximal (what is wrong right now) and distal causes can be deduced independently from each other. Indeed, Jackson et al. argue that common architectural issues in AD and DD can be established using CN. Bishop on the other hand postulates against this as deficits are focused on while intact processes are neglected. Further, top-down and bottom-up interactions are dismissed. Karmiloff-Smith (1998) deems these highly relevant for understanding DD. Thirdly a uniform modularity is assumed without accounting for alterations in development. Bishop proposed that AD should be researched using single-case double-dissociations while for DD, as they are likely to demonstrate associated deficits, group studies are recommended. Problematically, the debate on what constitutes a module has not been clarified yet (e.g. Fodor (2000): encapsulation, Coltheart (1999): domain specificity). Until this is established functional models and CN will not carry valid explanations nor reveal (mal)development well (Thomas et al., 2002). This underpins the view against exploring DD within a CN framework. Additionally, modularity/plasticitys scope of variation in DD and AD remains unestablished (Tager-Flusberg, 2000; Thomas et al., 2003). Humphreys, Ewing, and Karmiloff-Smith (2002) proposed the example of Williams syndrome patients possessing intact face recognition which is, however, achieved by applying processes diverging from typicality. Initially, face recognition was seen as intact despite visuospatial deficits, reduced sensitivity to inverted faces and lack of progressive development of localisation (Grice, Spratling, Karmiloff-Smith, Halit, Csibra, De Haan, Johnson, 2001). Hypothetically, assuming RN, this could be seen as double-dissociation between developmental prosopagnosia and WS. Basing modelling of DD on highly debated assumptions poses a problem for validity of the framework. Additionally, CN is accused of focusing on representational (competence) rather than processing (performance) deficits (Bishop, 1997). This, however, appears to be crucial in terms of applying research to DD. Weigelt, Koldewyn, and Kanwisher (2012) demonstrated a lack of qualitative difference (how facial identity is discriminated or remembered, competence) but rather a quantitative (how well, performance) difference in that ASD patients are impaired in memory and perception despite indication of intact face identity recognition. According to Bishop, this is another argument against applying CN to exploring DD. Concluding then, the much debated assumption of modularity held in cognitive neuropsychology overshadows exploration of disruptions during the trajectory of neuronal development. Applying double-dissociations to DD arguably yields invalid results and is more suited to acquired disorders. This is due to the assumptions within CN of Residual Normality, directionality of impact within disorders and its dependence on localisation of disruption, universality of localisation, neglect of plasticity and the focus on (in)competence. All in all, it has been proposed, while certain aspects could be overlooked, connectionist models rather than functional models would yield better results. Also, cognitive neuropsychology focuses on adult processes thus damage after complete development which is hard to match onto disorders of development. In order for CN to account validly for disorders, different models have to be applied for acquired and developmental cases.

Out of the Darkness: Female Genital Mutiliation Essay -- Womens Righ

Since the 1790s, women have been struggling to overcome the confines imposed on them by dominant patriarchal societies. (Andrea and Overfield 257). Much advancement has been made as women have continued to bring to light their views and ultimate demand for equality with respect to their male counterparts (Andrea and Overfield 260). Despite how far they have come, feminist today find themselves combating the violation of women’s rights regarding the cultural tradition of female circumcision, which some feel is more appropriately referred to as female genital mutilation (FGM) (Johnsdotter and Ensà ©b 30). Millions of women and children have been and continue to be subjected to the barbaric act of FGM, which not only leaves their bodies disfigured, but carries lifelong significant health risks and in some cases even ends in death (Morrison 125, 128). After researching a multitude of documents and case studies regarding the practice of FGM, it is evident that feminist are war ranted in their alarm and even disgust, when faced with the knowledge that this practice is continuing to be uph...

The Grapes of Wrath- Symbolism Essay

Symbolism Symbols are often used to represent bigger ideas and concepts in a novel. In The Grapes of Wrath, there are many symbols to represent the lives of not only the Jode family but the migrants as a whole. Steinbeck uses the symbols of the dust and the turtle to show the struggles of the migrants and how they overcame all odds, revealing the only hope the migrants had to survive the harsh trek cross country was perseverance. The dust is the first significant symbol Steinbeck uses to represent the migrants and their struggles. As the dust filled the air in Oklahoma, families watched their lives settle to nothing along with the dust, â€Å"The men were silent and they did not move often. And the women came out of the houses to stand beside their men– to feel whether this time the men would break† (3). The dust is symbolic of the migrant’s lives eroding to nothing. It represents not only mother natures roll in the horrible tragedy of the crumbling families, but also represents the banks and large plantations that took over the small and venerable families and farms just like the dust engulfed their homes. Though the migrants went through so much with losing their farms, homes, and lives, they still stood strong and found a way to keep moving forward, â€Å"After a while the faces of the watching men lost their bemused perplexity and became hard and angry and resistant† (3). The migrant families overcame their struggles with the dust over taking their homes along with all of the other struggles they faced, and they moved west for a new life. On their journey west, the migrants faced many challenging obstacles that they had to persevere through. Steinbeck uses the symbolism of the turtle to represent the stubborn migrants fighting their way west, â€Å"And over the grass at the roadside a land turtle crawled, turning aside for nothing, dragging his high-domed shell over the grass† (14). The turtle was set back by both nature and man on his journey across the road, just like the migrants were on their long trek westward. The turtle faced a red ant, barely escaped death by a car twice, and had to struggle with rough terrain along with flipping himself upright after being flipped over by the front wheel of a ruck. Like the migrants overcoming sickness, death, car problems, money shortage, unfair merchants, and lack of work, the turtle also overcame all of his challenges and setbacks and continued to persevere on his path, â€Å"Its front foot caught a piece of quartz and little by little the shell pulled over and flopped upright†¦ The turtle entered a dust road and jerked itself along, drawing a wavy shallow trench in the dust with its shell. The old humorous eyes looked ahead†¦Ã¢â‚¬  (15). Even though the turtle had several setbacks, he still held his head high and looked forward down the path he was traveling, never forgetting where he was going just like the migrants. The dust and the turtle symbolize the journey of the migrants starting from the moment they were kicked out of their homes. The turtle is a better representation of how hard the migrants fought to reach their final destination, just to find they had to fight to live one day at a time. The dust is the best symbol Steinbeck uses to represent the bigger farms and natures roll in the future of the migrants. However both symbols represent the bigger picture, the perseverance the migrants had to use to survive each day on their journey, and each hour once they reached their overpopulated destination of California.

The traditional material known as aluminum

The traditional material known as aluminum is often too soft to meet the requirements of certain applications, especially when considering aeronautic applications. These structural demanding applications thereby require the making of aluminum alloys which are structurally tough materials. Aluminum alloys are made to increase mechanical strength, increase corrosion resistance of the material, and thus increase overall shock survivability of the material (Subodh, K. D. , 2007).Here, we are concerned with Aluminum alloys 2024 and 7075 which are particularly used in aircraft structures, and aerospace applications. The review presents the similarities and differences of each material with regards to their chemistry, processing, and heat treatment measures. Aluminum 2024 The aluminum 2024 was first introduced in 1931, and was available as an alclad sheet and plate forms. Due to its high corrosion resistance, the material is often used in areas of an aircraft where fatigue resistance and st rength are required. Those areas include fuselage, wings, shear webs, and ribs of an aircraft.As an alloy, aluminum 2024 is made up of several materials among which are aluminum, chromium, copper, iron, magnesium, manganese, zinc, and silicon. Such a composition gives the ending material adequate mechanical and thermal properties demanded for aircraft structural components. However, the material is also used for truck wheels, screw machine products, scientific instruments, and orthopedic equipment. Overall, the aluminum 2024 material may be used in any application where there is a need for high strength to weight ration materials, and/or structures.

Free Essays on Cyber Criminals

A young teen calling himself â€Å"Mafiaboy† was arrested in Montreal, Canada early April of 2000. His crime? He was charged with at least one of the Denial-Of-Service (DoS) hacker attacks that blocked access to such popular sites as Yahoo!, Amazon, and eBay. –â€Å"Dembeck† Thirty years ago, a juvenile delinquent like â€Å"Mafiaboy† would be reduced to say, setting a mailbox on fire or some other adolescent prank. Now, with today’s technology, his â€Å"adolescent prank† disrupted world wide E-commerce and attracted massive media attention. Hackers like â€Å"Mafiaboy† are becoming more and more abundant these days, and are finding more innovative ways to accomplish their wide variety of goals. Their goal may be to send a virus to the computer of someone they dislike. Some of these â€Å"Cyber Criminals† hack into websites and destroy information, others hack into government or company computers, steal money and information, pirate software and more. There are many forms of computerized crime; most computer crime can be traced back to one common tool (besides a computer of course) the Internet. Yes, the same information super-highway that is used by millions of people everyday has become, to a hacker, nothing more than a gateway to easy, and thanks to up-to-date technology, relatively safe criminal mischief. The Internet is used for many good things, and is an irreplaceable tool for today’s world commerce, but thanks to cyber criminality, it is also a dangerous weapon that threatens that same commerce and even the security of the civilized world. There are about five main types of computerized crime. Illegal or offensive material is the first and one of the most common types. This is where the â€Å"criminal† posts illegal or offensive information or material on websites, netgroups, etc. Another common form of cyber crime is sending threatening or offensive e-mails. Sending ANY e-mail that appears to be threatening in nature, ... Free Essays on Cyber Criminals Free Essays on Cyber Criminals A young teen calling himself â€Å"Mafiaboy† was arrested in Montreal, Canada early April of 2000. His crime? He was charged with at least one of the Denial-Of-Service (DoS) hacker attacks that blocked access to such popular sites as Yahoo!, Amazon, and eBay. –â€Å"Dembeck† Thirty years ago, a juvenile delinquent like â€Å"Mafiaboy† would be reduced to say, setting a mailbox on fire or some other adolescent prank. Now, with today’s technology, his â€Å"adolescent prank† disrupted world wide E-commerce and attracted massive media attention. Hackers like â€Å"Mafiaboy† are becoming more and more abundant these days, and are finding more innovative ways to accomplish their wide variety of goals. Their goal may be to send a virus to the computer of someone they dislike. Some of these â€Å"Cyber Criminals† hack into websites and destroy information, others hack into government or company computers, steal money and information, pirate software and more. There are many forms of computerized crime; most computer crime can be traced back to one common tool (besides a computer of course) the Internet. Yes, the same information super-highway that is used by millions of people everyday has become, to a hacker, nothing more than a gateway to easy, and thanks to up-to-date technology, relatively safe criminal mischief. The Internet is used for many good things, and is an irreplaceable tool for today’s world commerce, but thanks to cyber criminality, it is also a dangerous weapon that threatens that same commerce and even the security of the civilized world. There are about five main types of computerized crime. Illegal or offensive material is the first and one of the most common types. This is where the â€Å"criminal† posts illegal or offensive information or material on websites, netgroups, etc. Another common form of cyber crime is sending threatening or offensive e-mails. Sending ANY e-mail that appears to be threatening in nature, ...

The meninas essays

The meninas essays Late in his life, in 1656, Velzquez painted what is his acknowledged masterpiece, "Las Meninas" or the "Maids of Honor". Here he provided his own original essay on the nature of reality by fusing several subjects. The group portrait, the "genre" (scenes of everyday life) theme, the self-portrait, the artist in the studio and the interior... have all come together in a new and distinctive form. "The Maids of Honor" is, in fact, a series of portraits within portraits. It is first a portrait of a room: the artists studio.... Gathered in the room are the Infanta Dos space. They, in fact, may be the subject of a double portrait being painted on the canvas upon which Velzquez shows himself working the artist in his studio has been woven into the scene. "Las Meninas" hung in Phillips private office, a sure indication that it was special to him. Here, in a single image, much that was important to Phillip was ingeniously brought together. His family, his retainers (servants), his newly knighted painter, and above all, his beautiful daughter are gathered in the room that belonged to his dead son and heir. In an image both charming and melancholy, Velzquez has captured the waning years of the Spanish Hapsburgs. Velzquez died only four years later, and Phillip died in 1666. During the years...

Sentence Building with Appositives

Sentence Building with Appositives If you have read How to Build Sentences With Appositives and Practice in Identifying Appositives, you should be well prepared for these sentence combining exercises. Instructions Combine the sentences in each set below into a single clear sentence with at least one appositive. Omit words that are needlessly repeated, but dont leave out any important details. If you run into problems, you may find it helpful to review the following pages: Introduction to Sentence CombiningWhat Is an Appositive?Practice in Identifying Appositives When youre done, compare your new sentences with the sample combinations on page two. Keep in mind that many combinations are possible, and in some cases you may prefer your own sentences to the original versions. Monroe and I strolled through the graveyard.The graveyard is the most peaceful spot in town.St. Valentine is the patron saint of lovers.St. Valentine was never married.We were waiting outside the prison cells.The cells were a row of sheds fronted with double bars.The cells were like small animal cages.My father was outside.My father was beneath the window.My father whistled for Reggie.Reggie was our English setter.We saw the stream in the valley.The stream was black.The stream was halted.The stream was a tarred path through the wilderness.We arrived at a group of peasant houses.The group was small.The houses were low yellow constructions.The houses had dried-mud walls.The houses had straw mats.A great many old people came.They knelt around us.They prayed.They included old women with jet-black faces.The women had braided hair.They included old men with work-gnarled hands.One of the Cratchet girls had borrowed the books.She was a hatchet-faced girl.She was thin.She was eager.She was a transplanted Cockney.She had a frenzy for reading. It was the kind of home that gathers memories like dust.It was a place filled with laughter.It was filled with play.It was filled with pain.It was filled with hurt.It was filled with ghosts.It was filled with games.I led a raid on the grocery.It was the grocery of Barba Nikos.The grocery was small.The grocery was shabby.Barba Nikos was old.Barba Nikos was short.Barba Nikos was sinewy.Barba Nikos was a Greek.Barba Nikos walked with a slight limp.Barba Nikos sported a flaring handlebar moustache. When you are done, compare your new sentences with the sample combinations on page two. On this page youll find answers to the exercises on page one, Sentence Building With Appositives. Keep in mind that in many cases more than one combination is possible. Monroe and I strolled through the graveyard, the most peaceful spot in town.St. Valentine, the patron saint of lovers, was never married.We were waiting outside the prison cells, a row of sheds fronted with double bars, like small animal cages.(George Orwell, A Hanging)Outside beneath my window, my father whistled for Reggie, our English setter.We saw the stream in the valley, black and halted, a tarred path through the wilderness.(Laurie Lee, Winter and Summer)We arrived at a small group of peasant houses, low yellow constructions with dried-mud walls and straw roofs.(Alberto Moravia, Lobster Land: A Traveler in China)A great many old people came and knelt around us and prayed, old women with jet-black faces and old men with work-gnarled hands.(Langston Hughes, Salvation)One of the Cratchet girls had borrowed the books, a hatchet-faced, thin, eager, transplanted Cockney girl with a frenzy for reading.(Wallace Stegner, Wolf Willow)It was the kind of home that gathers memories like du st, a place filled with laughter and play and pain and hurt and ghosts and games.(Lillian Smith, Killers of the Dream) I led a raid on the small, shabby grocery of Barba Nikos, a short sinewy Greek who walked with a slight limp and sported a flaring, handlebar moustache.(Harry Mark Petrakis, Stelmark: A Family Recollection)

TED talk Movie Review Example | Topics and Well Written Essays - 250 words

TED talk - Movie Review Example presentation content is of much significance; nonetheless, I hold the opinion that the style of presentation is more important, as it goes a long way in guaranteeing the concentration of the audience. There is no doubt that body language can enhance the delivery of a given content. This is because even the utmost dazzling arguments can send the listeners to slumber if the speaker is uninteresting and downbeat in tone (Knapp et al, 2014). On the other hand, a vibrant one with affirmative body language and changing tone often comes across as well versed, even when their subject of discussion is not attractive. It is indeed true that a polished presentation can compensate for weak content. That notwithstanding, I hold the opinion that both Allan Pease and Amy Cuddy were well informed on their topics of discussion, and their outstanding presentation skills supplemented the entire productions. Over and above, both the presentations have encouraged me to pay significant attention to nonverbal aspects of presentations, as the way in which an individual paces, stands, waves the hands and even moves the head drive countless

Privacy Essay Example | Topics and Well Written Essays - 1250 words - 1

Privacy - Essay Example The government and other influential people have been very vocal in monitoring social networks, arguing that it helps the government understand how the public is receiving its policies and practices (Rennie). For instance, the UK government has responded to a law suit brought to court by a civil rights agent about privacy by saying that the government has a right to carry out what they call legal spying. (Queally, Para 1). Americans are also not left behind. According to Damon (Para 1), the US government is working with social media companies to plan for back-doors to help government spy in peoples social media accounts. This shows that governments are increasingly looking to spy on people’s live through social media. Although there may be an advantage for allowing the government to access personal information for investigation purposes, the problem is that this is prone to abuse. At the same time, the basic principle of justice and liberty require that the freedom of an indiv idual should not be scarified, not even when it is for the good of the public. In this regard, the government should look for alternative ways to do their investigation, and not interfere with the private lives of everybody else. No one should ever have the moral authority to interfere with people’s privacy, not even for the sake of national security. I believe that it is obscene for the government to look through people’s private information on social networks and phones because this goes against the constitutional right that guarantees privacy of individuals. Invading people’s privacy on the social networks and mobile phones by the government is a heinous practice that might result in illogical judgment about the social networks users. For example, most young people use the social media for dating and organizing youth oriented events. The dating language might look immoral to the government and parents, but the sender and

Fitness & Wellness Research Paper Example | Topics and Well Written Essays - 1250 words

Fitness & Wellness - Research Paper Example This paper approves that wellness consists of the physical, mental, and spiritual well-being social, emotional, spiritual, environmental, occupational, intellectual and physical wellness. For example physical wellness is related to our daily activities and whether we do exercise on a daily basis. This involves aspects such as riding a bicycle at least 30 minutes a day, doing a walking routine or even doing the stairs at work instead of using the elevator. It also involves taking and maintaining healthy habits such as checkups, a balanced diet and exercise and staying away from bad habits such as tobacco, drugs and alcohol. This essay makes a conclusion that this involves physical fitness together with nutrition and self drive which is easier with consistency in physical activity. Attaining this kind of lifestyle involves eating a healthy diet that leads to reducing fat intake, sugars and sodium. A healthy diet consists of whole grains, fruits and vegetables. For meat, it’s recommended to take lean meats such as beef, lamb, fish and poultry and low fat and/or fat free dairy products. Processed and refined foods should be avoided. Best solution is to prepare your own food at home for the nutritional content.Avoiding alcohol, drugs and tobacco as excessive consumption can lead to severe effects. Physical activity is a key to longevity. Individuals should plan on implementing wellness programs such as aerobics, jogging, kick boxing and many more to their schedule. Again choosing an activity that you enjoy is essential or progress. Also incorporate aspects such as strength training that help for longevity, balance, and fitness.

VAMPIRE SOCIAL FEAR Essay Example | Topics and Well Written Essays - 1250 words

VAMPIRE SOCIAL FEAR - Essay Example The concept of the existence of vampires was further glorified by eminent classic and contemporary literature authors that have created frenzy amongst the masses regarding the existence of these creatures. (Belanger, 2005, p. 49) As mentioned earlier, on a literary front the idea of vampires have fascinated, amazed and scared people throughout the ages. The belief in the existence of demons and spirits has been a prime aspect of all faiths and are often deemed to be the forerunners of the creation and concept of vampires; a dead blood-sucking nocturnal being that is largely associated with evil and the damned. Roman, Greek and Mesopotamian cultures all had a common notion regarding the existence of vampires but the concept itself gained more shape in Eastern Europe, where the legends narrated that vampires were revenants of sinner, suicide victims, people involved in witchcraft and corpses under the possession of malicious spirits or people who died of vampire bites. There were count less speculation regarding the appearance of vampires and before human physical features were used to typify Vampires, they were vastly believed to bestial creatures, which were damned for the rest of eternity and their existence was only meant to plague the living. The Description of the appearance of vampires is illustrated immaculately by the following quote from Sacred Hunger authored by Michelle Belanger, a self-proclaimed Psychic-vampire, who has published several books on this entire concept and has demonstrated the contrasts between the media portrayal and folkloric image of vampires, she states, â€Å"The vampire has come a long way since its beginnings in folklores†¦ Though, monstrosity in their hungers there is an ineffable something that inspires their so-called ‘Victims’ to willingly open their veins. Yet in stark contrast, the vampires we encounter in the tales of Eastern Europe are little more than corpses. These foul and bestial monsters terrorize whole villages, filing their victims with horror and disgust.†(Belanger, 2005, p. 14) Therefore, from the aforementioned quote it is abundantly clear that there is a huge schism between the perception of vampires in contemporary and the portrayal of folklores. Belanger has defined the true meaning of vampirism and the prevalence of this belief in gothic sub-cultures. It has become more of an identity for people and the term ‘vampirism’ itself is not used to signify bestial behavior or monstrosity, and is now given similar connotations as people who are left-handed; the latter due to the widespread belief that left-handed people are evil. The aforementioned analogy describes that vampirism is no longer emblematic of a blood-thirsty creature but all those people who are in pursuit of vital energy. However, this is still a subjective approach to the subject and having mentioned the prose will focus its attention back to the area under discussion that is whether or no t the social fear derived from these creatures is in anyway valid and the amount of insight provided by literature and conception of fictional characters to demonstrate this aspect. Therefore, the substance of the following prose will juxtapose the folkloric illustration of these creatures and how authors have portrayed the image of these creatures. In order to gain greater amount of insight in to the subject, the prose will

Comparative paper examining some aspect of the legal regime governing Essay

Comparative paper examining some aspect of the legal regime governing media in Hong Kong and in the United States - Essay Example Under this principle, the media are the voice of the ruling Party and play by its rules and policies. Apart from that, the Party controls all activities of the media that pertains to news production and delivery to the public. Thus, the media only delivers what is authorized by the Party to the public. On the contrary, in America, the media operates freely with minimal interference from the government. Additionally, the media functions as a â€Å"watchdog,† which evaluates and monitors the actions and activities of the government. Defamation laws in these two countries clearly bring out the differences and similarities in media activities and regulations in America and China. Defamation in law is the act of making statements about a person, which damages the reputation of the individual in question. When in written format, defamation is referred to as â€Å"libel† and â€Å"slander† when in spoken form. In order to understand how defamation law works in China, it is essential to explore the structure and function of the legal system in China as it pertains to matters of the media. Thus, the first section of this paper will explore the legal system in China while drawing on any similarities and differences with the United States legal system. The second section will look at the background of defamation law in the United States and Chinese, and finally, the last section will draw on comparison between defamation law in China and the United States. This provision is similar to what is found in the United States Constitution, and at first, one may think that the Chinese media enjoys the same rights as that in America. However, application of the Chinese Constitution is different from that of the United States constitution. Unlike the Americans, citizens of China enjoy neither economic nor civil rights enjoyed by their American counterparts. This ineffectiveness in the application of the Constitution in China is because of the

SONG love for sale by miles davis Essay Example | Topics and Well Written Essays - 250 words

SONG love for sale by miles davis - Essay Example hat take this form last nearly 4 minutes with a diminishing common tone and tri tone substitutions particularly between the fifth and seventh major and minor. Notably, this is described by A1-A2-B-A3. It is these changes between the majors and minors that lead to solo breaks in the song and such sections lust for nearly 30 seconds. This song is slightly different from other Jazz song despite being classified under the same song types. The difference lies mainly in the tonality where the Love for Sale takes â€Å"A† sections that are nearly 50/50 between the minor and major while â€Å"B† major primarily. Additionally, the song takes a slight different in its movement where it seems to employ skips and steps in both direction and these apply on a wide range on a fifth and an octave; however, the same does not take large leaps. Finally, it is worth noting that the song has three choruses that harmonizes and blends to the entire song. Notably, at (Davis) 04:20 and 06:40 minutes, Davis applies swings and vocals comping techniques with progressive chording. This makes this song from other bebop groups that only have one chorus throughout the

Comparative paper examining some aspect of the legal regime governing Essay

Comparative paper examining some aspect of the legal regime governing media in Hong Kong and in the United States - Essay Example Under this principle, the media are the voice of the ruling Party and play by its rules and policies. Apart from that, the Party controls all activities of the media that pertains to news production and delivery to the public. Thus, the media only delivers what is authorized by the Party to the public. On the contrary, in America, the media operates freely with minimal interference from the government. Additionally, the media functions as a â€Å"watchdog,† which evaluates and monitors the actions and activities of the government. Defamation laws in these two countries clearly bring out the differences and similarities in media activities and regulations in America and China. Defamation in law is the act of making statements about a person, which damages the reputation of the individual in question. When in written format, defamation is referred to as â€Å"libel† and â€Å"slander† when in spoken form. In order to understand how defamation law works in China, it is essential to explore the structure and function of the legal system in China as it pertains to matters of the media. Thus, the first section of this paper will explore the legal system in China while drawing on any similarities and differences with the United States legal system. The second section will look at the background of defamation law in the United States and Chinese, and finally, the last section will draw on comparison between defamation law in China and the United States. This provision is similar to what is found in the United States Constitution, and at first, one may think that the Chinese media enjoys the same rights as that in America. However, application of the Chinese Constitution is different from that of the United States constitution. Unlike the Americans, citizens of China enjoy neither economic nor civil rights enjoyed by their American counterparts. This ineffectiveness in the application of the Constitution in China is because of the

Music and Social Change Research Paper Example | Topics and Well Written Essays - 1250 words

Music and Social Change - Research Paper Example This paper will examine the reggae music genre, discussing its impact on society. Bob Marley, as well as other notable reggae artists, has a definite influence on the society as they advocate for social change through their music. During his brief life (1945-1981), Bob Marley rose from obscurity and poverty to international superstardom. Bob Marley remains the single third world artist to attain such worldwide acclaim. Bob Marley attained this status through charisma and ambition, and was it, not for these traits, reggae music would still be restricted to Jamaican ghettoes, which was its origin. Bob’s life changed when Haile Selassie visited Jamaica. Haile Selassie, the Ethiopian Emperor, was a cherished savior of Africans in Jamaica. Bob’s ideologies shifted after spending one year in America where he witnessed the evils of the free market, as well as the oppression of capitalism while working at a major corporation (Stephens 34). After returning to Jamaica, Bob established the Rastafarianism religion, which entailed wearing his hair in dreadlocks. Rastafarianism had a significant influence on Bob’s music as he sang about how the white race oppressed Africans. Bob’s main songs that speak to social change are Buffalo Soldier and Could You be Loved. Bob’s reputation transcended the controversy associated with his practice of Rastafarianism. He was regarded as a peacemaker, which is notable through his Smile Jamaica concert that sought to reduce tensions between rival gangs associated with two of the main national parties during an election period (White 124). Bob and his best friend Bunny wrote many songs that had a monumental impact on the Jamaican and global society. Bob used his music to send off messages of hope, love, and peace (Jah). At the end of all his songs, Bob Marley used the words â€Å"Jah Rastafari† to show his belief in Jah, i.e. peace and love.  

Design Of A Sulfuric Acid Production Plant Engineering Essay

Design Of A Sulfuric Acid Production Plant Engineering Essay This project is prepared according to the requirements of chemical engineering department, and its also a preliminary study of sulfuric acid production plant. The project begins with chapter one which includes introduction, definition of sulfuric acid and shows the main uses of sulfuric acid which have made it an important chemical in the world, followed by chapter two which talks about literature, market survey and the history and current processes for production the sulfuric acid also it gives small glimpse of the prices trends of the raw material and product. That is followed by description for various processes to produce sulfuric acid in chapter three, which ends with the selection of the best process which is the double contact process; the description and flow sheet of the selected process are discussed in chapter four. Material and energy balance results are listed in chapter five and the location of the plant is selected in chapter six by comparing different locations, and the best location for the plant (as its set in this report) is Aqaba city. . Finally, material and energy balance details are discussed in the appendix, that includes the used charts and references. CHAPTER ONE INTRODUCTION 1.1 Definition Sulfuric acid is a strong mineral acid with the molecular formula H2SO4. It is a clear, colorless, odorless, viscous liquid that is very corrosive. It is soluble in water at all concentrations. Sulfuric acid has many applications, and is one of the top products of the chemical industry. There are another names for sulfuric acid, it is sometimes called oil of vitriol.1 Its chemical formula is Figure (1.1.1): Sulfuric Acid Formula1 1.2 Physical and Chemical properties This table shows the main chemical and physical properties of sulfuric acid Sulfuric acid IUPAC Oil of vitriol Other name H2O4S Molecular formula 98.08 g molà ¢Ã‹â€ Ã¢â‚¬â„¢1 Molar mass Clear, colorless, odorless liquid Appearances 1.84 g/cm3, liquid Density 10  Ã‚ °C, 283  K, 50  Ã‚ °F Melting point 337  Ã‚ °C, 610  K, 639  Ã‚ °F Boiling point Miscible Solubility in water à ¢Ã‹â€ Ã¢â‚¬â„¢3 Acidity(pka) pungent odor Odor Non-flammable Flash point 26.7 cP (20  °C) Viscosity 0.3 Ph Table (1.2.1): physical properties1 1.3 Application and Uses Sulfuric acid is a very important chemical commodity, and indeed, a nations sulfuric acid production is a good indicator of its industrial strength. It is used as electrolyte in lead-acid batteries (accumulators) . It is important in the production of fertilizers such as ammonium sulfate (sulfate of ammonia), (NH4)2SO4, and superphosphate, Ca(H2PO4)2, which is formed when rock phosphate is treated with sulfuric acid. It is used to remove oxides from iron and steel before galvanising or electroplating . Concentrated sulfuric acid is used as a dehydrating agent, that is, to remove water, since it has a tendency to form hydrates such as H2SO4.H2O, H2SO4.2H2O. Sulfuric acid is used in the production of nitroglycerine, an inorganic ester organic nitrate, which is used as an explosive. It is used in petroleum refining to wash impurities out of gasoline and other refinery products. It is used in manufacturing of hydrochloric acid, nitric acid, phosphoric acid, ether, plastics, metal sulfates, cellophane, dyes, drugs, perfumes, disinfectants and even glue.1 This chart shows the distribution of using sulfuric acid Figure (1.3.1): Sulfuric Acid Distribution.1 Specification of raw materials sulfur, S, 16 Name, symbol, number 32.065g ·molà ¢Ã‹â€ Ã¢â‚¬â„¢1 Standard atomic weight Yellow colored lumps, crystals, powder, or formed shape Appearances Lumps 75-115 lbs./ft3 Powder 33-80 lbs./ft3 Bulk Density 388.36  K,à ¢Ã¢â€š ¬Ã¢â‚¬Å¡115.21  Ã‚ °C,à ¢Ã¢â€š ¬Ã¢â‚¬Å¡239.38  Ã‚ °F Melting point 717.8  K,à ¢Ã¢â€š ¬Ã¢â‚¬Å¡444.6  Ã‚ °C,à ¢Ã¢â€š ¬Ã¢â‚¬Å¡832.3  Ã‚ °F Boiling point Insoluble Solubility In Water Solid Physical State 1.819 g ·cmà ¢Ã‹â€ Ã¢â‚¬â„¢3 Liquid density at maps. Table (1.3.1): Physical Chemical Properties of Sulfur.1 CHAPTER TWO LITERATURE AND MARKET SURVEY 2.1 History and Current processes The discovery of sulfuric acid is credited to the 8th century chemist and alchemist, Jabir ibn Hayyan (Geber). The acid was later studied by 9th century Persian physician and alchemist Ibn Zakariya al-Razi (Rhazes), who obtained the substance by dry distillation of minerals including iron(II) sulfate heptahydrate, FeSO4 ·7H2O, and copper(II) sulfate pentahydrate, CuSO4 ·5H2O. When heated, these compounds decompose to iron(II) oxide and copper(II) oxide, respectively, giving off water and sulfur trioxide, which combine to produce a dilute solution of sulfuric acid. 1 This method was popularized in Europe through translations of Arabic and Persian treatises, as well as books by European alchemists, such as the 13th-century German Albertus Magnus.1 There are two major processes (lead chamber and contact) for production of sulfuric acid and it is available commercially in a number of grades and concentrations. The lead chamber process, the older of the two processes, is used to produce much of the acid used to make fertilizers; it produces a relatively dilute acid (62%-78% H2SO4). The contact process produces a purer, more concentrated acid but requires purer raw materials and the use of expensive catalysts. n both processes sulfur dioxide is oxidized and dissolved in water. The sulfur dioxide is obtained by burning sulfur, by burning pyrites (iron sulfides), by roasting nonferrous sulfide ores preparatory to smelting, or by burning hydrogen sulfide gas. Some sulfuric acid is also made from ferrous sulfate waste solutions from pickling iron and steel and from waste acid sludge from oil refineries. 1 2.2 Supply and Demand This table shows the production rates of sulfuric acid (in metric tones) in some countries at different years. Production of sulfuric acid in metric tones Year country 1994 1997 2000 2006 France 2227 2242 2269 1755 Germany 3380 3496 4898 4595 Greece 360 675 688 815 Italy 1228 1590 1043 1616 Spain 2348 2810 2418 3500 United kingdom 1225 1205 1058 447 Sweden 518 630 629 1010 Table (2.2.1): Production Rates of Sulfuric Acid.3 This table shows the production and sales amounts of sulfuric acid and the consumption rate of sulfur in Jordan from 2000 to 2005, these amounts in (ton/year). Sulfur consumption (ton/tear) Ù Sulfuric acid Year Sales (ton/year) Production (ton/year) 370925 43824 1108605 2000 309816 46614 919548 2001 351011 43307 1055208 2002 265865 51445 961208 2003 364301 49661 1102899 2004 346345 48323 1046540 2005 Table (2.2.2)Jordan Production, Sales and Raw Material Consumption.5 2.3 Prices trends of the raw material and product The global sulfuric acid market experienced an unprecedented rise and fall in pricing between fall 2007 and spring 2009. Consumption of sulfuric acid for fertilizers fell steeply in the second half of 2008 due to the collapse in the global economy. The second half of 2009 is expected to experience almost flat to slightly positive growth, anticipating the improvement in market conditions in 2010. Trade is expected to fall globally, except for Southeast Asia, which would continue to depend on imports. As of early spring 2009, the market is continuing to deteriorate as the supply shortage situation has been replaced by product oversupply in almost all regions. And the world sulfuric acid supply trends are shown in the following chart. Figure (2.3.1): World Sulfuric Acid Supply.2 CHAPTER THREE PROCESS SELECTION Process Selection Sulfuric acid is an important raw material used in many industrial processes, such as phosphate fertilizer production and to a much lesser extent for nitrogen and potassium fertilizers, sulfuric acid is produced by catalytic oxidation of sulfur dioxide to sulfur trioxide, which is subsequently absorbed in water to form sulfuric acid. There are no major variations of commercial interests on this mentioned chemistry. There are alternatives as to source of Sulfur dioxide and method of conversion to sulfur trioxide. The two most common methods for the conversion of sulfur dioxide to sulfuric acid are: 1. Lead Chamber Process. 2. Contact Process 3.1 Lead Chamber Process This is an old process and was introduced in Europe in near the middle of 18th century, its used to produce much of the acid used to make fertilizers; it produces a- relatively dilute acid (62%-78% H2SO4).The classic lead chamber process consists of three stages: Glover tower, lead chambers and Guy-Lussac Tower. In this method hot sulfuric dioxide gas enters the bottom of the reactor called a Glover tower where it is washed with nitrous vitriol (sulfuric acid with nitric oxide, NO, and nitrogen dioxide, NO2, dissolved in it) and mixed with nitric oxide and nitrogen dioxide gases. The Glover tower serves two functions: concentration of the chamber acid and stripping of nitrogen oxides from the liquid to the gas. Concentration of the chamber acid (62% to 68% H2SO4) is achieved by the hot gases entering the tower which evaporate water from the acid. Some of the sulfur dioxide is oxidized to sulfur trioxide and dissolved in the acid wash to form tower acid or Glover acid (about 78% H2SO4). The dissolved nitrogen oxides are stripped from the acid and carried with the gas out of the Glover tower into the lead chambers. From the acid tower a mixture of gases (including sulfur dioxide and trioxide, nitrogen oxides, nitrogen, oxygen, and steam) is transferred to a lead-lined chamber where it is reacted with more water. Sulfuric acid is formed by a complex series of reactions; it condenses on the walls and collects on the floor of the chamber. There may be from three to twelve chambers in a series. The acid produced in the chambers, often called chamber acid or fertilizer acid, contains 62% to 68% H2SO4. After the gases have passed through the chambers they are passed into a reactor called the Gay-Lussac tower where they are washed with cooled concentrated acid (from the acid tower); the nitrogen oxides and unreacted sulfur dioxide dissolve in the acid to form the nitrous vitriol used in the acid tower. Remaining waste gases are usually discharged into the atmosphere. Product acid at a concentration of 78% H2SO4  is drawn from the cooled acid stream that is circulated from the Glover tower to the Guy-Lussac tower.   Nitrogen losses are made up with nitric acid which is added to the Glover tower. The major disadvantage includes the limitations in throughput, quality and concentration of the acid produced, also the environmental pollution. Figure (3.1.1): Typical process flow sheet for the lead Chamber. 3.2 Contact Process Because of economic reasons Contact plants are widely used compared to the lead plants, they are classified according to the raw materials charged to them: elemental Sulfur burning, spent sulfuric acid and hydrogen sulfide burning, and metal sulfide ores and smelter gas burning. The contributions from these plants to the total acid production are 81, 8, and 11 percent, respectively. The contact process incorporates three basic operations (stages), each of which corresponds to a distinct chemical reaction. First, elemental sulfur is received in a solid form containing various impurities. The sulfur is melted in the sulfur melter in the presence of hydrated lime which neutralizes any acidity present in the sulfur. This neutralization prevents problems of acid corrosion which would otherwise be encountered. Heat for the melting of the sulfur is supplied from steam coils. The molten sulfur is kept agitated to improve heat transfer, to prevent solids settling on the bottom of the sulfur pits and to prevent a crust forming on top. The dirty sulfur is filtered to remove impurities present and after filtering is transferred to the clean sulfur pit where it is kept molten until it is pumped to the burner. Molten sulfur at a temperature of 130 °C is sprayed into the burner in the presence of warm, dry air. The sulfur burns, forming sulfur dioxide S + O2 â‚ ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚   SO2 à ¢Ã‹â€ Ã¢â‚¬  H = -300 kJ mol-1 The resulting sulfur dioxide is fed to a process unit called a converter, where it is catalytically oxidized to sulfur trioxide (SO3): 2SO2 + O2 â‚ ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  2SO3 ΆH = -100 kJ mol-1 Its apparent that the equation gives a decrease in volume; this reaction would be aided by pressure. High conversions are however, obtainable with catalysts at 400 to 500oC with a small excess of oxygen and the use of pressure. The available methods to maximize the formation of SO3: As this is an exothermic process, a decrease in temperature by removal of the heat will favour the formation of SO3. Increased oxygen concentration. SO3 removal (as in the case of the double absorption process). Increased pressure. Catalyst selection, to reduce the working temperature (equilibrium). Longer reaction time. In the contact processes, the sulfur dioxide is converted to sulfur trioxide by the use of metal oxide catalyst, the characteristics of the used catalyst are: Porous carrier having large surface area, controlled pore size and resistance to process gases at high temperature; in pellet form if used in fixed bed and powdered form if used for fluidized bed. Ex- Alumina, silica gel, zeolites. Active catalytic agent: Preparations are generally kept secret for the competitive reasons but they usually consist of adding water soluble compounds to gels or porous substrates and firing at temperature below the sintering point. Promoter: Alkali and/or metallic compounds added in trace amounts to enhance the activity of the catalytic agent. A catalyst, vanadium pentoxide (V2O5) is used to increase the reaction rate because its relatively immune to poisons, also because of its low initial investment and only 5% replacement per year. It is only effective above its melting point of 400  °C. The greatest conversion of SO2 to SO3 is reached by passing the gas over several catalyst beds, cooling the gas between each pass so that the reaction temperature remains between 400 and 500  °C. As can be seen the figure. The disadvantages of using the V2O5 catalyst are that it must use dilute SO2 input (7-10%), as a catalyst it is less active and requires high oxygen or sulfur dioxide to give economic conversions also it requires larger converters and thus higher initial investment. Finally, the sulfur trioxide is absorbed in to very concentrated sulfuric acid (a 98-99 percent solution of H2SO4 in water), This operation takes place in the absorbing tower where the gas travels up through the tower, counter-current to the acid falling from the top of the tower producing a thick fuming liquid called oleum, the oleum is mixed carefully with water to avoid producing fine mist of sulfuric acid that is difficult to condense and could escape to pollute the air, the sulfur trioxide in the oleum reacts with the water as follows: SO3 + H2O â‚ ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  H2SO4 à ¢Ã‹â€ Ã¢â‚¬  H = -200 kJ mol-1 It is clear that the reaction is exothermic and the absorbing sulfuric acid has to be cooled continuously; the heat is available at a relatively low temperature and is not worth recovering. The efficiency of the absorption step is related to : The H2SO4 concentration of the absorbing liquid. (98.5 99.5%). The temperature range of the liquid (normally 70 -120 0C). The technique of the acid distribution. The raw gas humidity (mist passes the absorption equipment). The mist filter. The temperature of incoming gas. The co-current or countercurrent character of the gas stream in the absorbing liquid. Main disadvantages of the contact process are that concentrated acid (98%) of high purity can be produced directly and that compact plants of quite high capacity have now become rather common place. The contact process can be applied in different techniques; three of those techniques are described in the following sections 3.2.1 Single contact / single absorption process After purification and drying, the SO2 is converted to SO3 using a series of four catalyst beds, containing alkali and V2O5. Afterwards, the SO3 is absorbed in concentrated sulfuric acid and, if necessary, an oleum absorber is installed upstream. SO3 reacts with the water contained in the absorber acid to yield H2SO4. The absorber acid is kept at the desired concentration of approximately 99% w/w by addition of water or dilute H2SO4. The single contact/single absorption process is generally used for gases with an SO2 Content from 3 6 %. New single contact plants are built only for inlet gases with substantial fluctuation of the SO2 content. The investment cost of this technique is low compared to the investment cost of double contact plants. Figure (3.2.1.1): Typical process flow sheet for a single catalysis plant. 3.2.2 Double Contact/ Double Absorption Process The double contact process was implemented to develop the single contact/single absorption process. In this process a primary SO2 conversion of 85 95 % is achieved in the first catalysis stage of the converter before entry into an intermediate absorber, depending on the arrangement of the converter beds and the contact time. What makes the double contact/double absorption process more advantageous is that its ability to feed gases with higher SO2 concentrations than would be possible with the single catalysis process. Which leads to smaller gas volumes and therefore smaller equipment with comparable production capacities. This results in a considerably higher conversion rate, if the residual gas is passed through the following converter beds (usually one or two). The SO3 which is formed in the second catalysis stage is absorbed in the final absorber. In general the process uses gases with an SO2 content of 10 t o11 %. The inlet gas temperature is about 4000C. Gases with lower temperatures require reheating from 50 to 4000C. This is usually carried out with recovered heats from the conversion process. Operating the double contact process at an elevated pressure of 5 bar increases the conversion rate by shifting the conversion equilibrium and favouring the formation of SO3. The disadvantages are higher electricity consumption and, at the same time, less steam production. Higher NOx emissions are caused by higher sulfur combustion temperatures (18000C), but savings of 10 -17 % on investment costs are gained. Figure 3.2.2.1: Typical process flow sheet for a sulfur burning double catalysis plant. 3.2.3 Wet catalysis process The wet catalysis process is applicable to wet SO2 gases. The potential for the formation of sulfuric acid mist might require tail gas treatment. Wet SO2 gases (eg. from the burning of H2S gases or from the catalytic conversion of H2S gases) are directly supplied into the contact tower without previous drying. SO3 formed by the catalytic conversion immediately reacts with the moisture of the gases, thereby forming the acetic acid. The sulfuric acid is condensed in a condenser installed after the contact tower. Factors Sulfuric Acid Production By Lead Chamber process Sulfuric Acid Production By single contact/single absorption process Sulfuric Acid Production By double contact/double absorption process Sulfuric Acid Production By Wet Catalysis process Health and safety hazards involved Less safe, waste gases are discharged to the atmosphere Less amount of SO3 is absorbed so the rest is discharged to the atmosphere A larger amount of SO3 is absorbed A larger amount of SO3 is absorbed Operating cost High operating cost Less operating The least operating cost Less operating cost Raw material SO2, NO, NO2, O2, H2O. Melted sulfur, O2, SO2, SO3. Melted sulfur, H2O, O2, SO2, SO3. Wet SO2 gases, H2S, O2, SO3. Waste products and by products Exhaust gases are discharged to the atmosphere Large amounts of SO2 gas are discharged to the atmosphere Less amounts of SO2 gas are discharged to the atmosphere, less heat released after each successive catalyst bed. A larger amount of SO3 is absorbed Equipment Acid Tower (Glover Tower), Lead Chambers, Reactor (Gay-lussac Tower) Air dryer, burner, waste heat boiler, converter, single absorption column. Air dryer, burner, waste heat boiler, converter, intermediate and external absorption column. Burner, convertor, acid tower. Yield Yields 78% H2SO4 New plants achieve 98 to99 % conversion rates Yields about 98% Yields 70 to 80 % H2SO4   Environmental pollution More gases are discharged to the atmosphere More gases discharged to the atmosphere Less gases discharged to the atmosphere More gases are discharger to the atmosphere Purity of products Low purity Low purity High purity Low purity Table (3.2.1): Process selection Factors Sulfuric Acid Production By Lead Chamber process Sulfuric Acid Production By single contact/single absorption process Sulfuric Acid Production By double contact/double absorption process Sulfuric Acid Production By Wet Catalysis process Health and safety hazards involved 5 5 5 3 Operating cost 6 4 7 5 Raw material 6 5 7 5 Waste products and by products 6 6 7 5 Equipment 7 5 8 6 Yield 5 6 7 9 Environmental pollution 5 5 6 4 Purity of products 6 5 7 9 Total (80) 46 41 54 46 Table (3.2.2): Process Selection According to the discussion and the data presented above we choose the Double Contact/Double Absorption process. CHAPTER FOUR PROCESS DISCRIPTION 4.1 Production of H2SO4 by double contact process The process begins in the burner, in which the melt sulfur is pumped to the burner where it is burnt in an excess of dry air. The gas exiting the burner is maintained at (8 9%v/v) sulfur dioxide and approximately 830 °C due to the heat produced by the exothermic reaction. Sulfurs on burning gives about one third of heat combustion of coal ,and this heat raises the temperature of combustion gases roughly in accordance with the figure (4.1.1) as shown. Figure (4.1.1): Theoretical Flame Temperature.8 This heat is high in temperature and there is plenty of it, consequently it is worth utilizing and the hot gases are led across pipes through which the water passes. The water is heated, steam is raised and the gases are cooled. The sulfur dioxide/air gas mixture is then passed through the stream to converter. The sulfur dioxide is converted to sulfur trioxide by reacting with oxygen over a catalyst. This reaction is described by the equation: 2SO2 + O2 â‚ ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  2SO3 ΆH = -100 kJ mol-1 This reaction occurs in the converter, a four-stage reaction vessel with each stage consisting of a solid catalyst bed through which the gas is passed. The catalyst used is vanadium pentoxide (V2O5), and potassium sulphate dispersed on a silica base which forms a porous support, giving a large surface area for reaction. This reaction is exothermic and its equilibrium constant decreases with increasing temperature (Le Chatelier.s Principle). Figure (4.1.2) shows the percentage conversion of SO2 to SO3 that would be reached at an SO2 concentration of 8% v/v and a range of gas temperatures. However, the reaction rate is also temperature dependent, so that if the temperature becomes too low the equilibrium point will not be reached. In practice, the gas temperature must be maintained between (400 500 °C) to maintain a high reaction rate and also high conversion equilibrium. As the reaction is exothermic, heat is generated across each of the catalyst beds. This heat must be removed between each stage to maintain the optimum reaction temperature into the following stage. The temperature rise through each catalyst bed and the inter-stage cooling is shown in Figure (4.1.2). Figure (4.1.2): The Temperature Rise Through Beds.7 The gas after passing through three catalyst bed goes to the first absorption tower where the Sulfur trioxide is removed. The gas is then reheated to about 420 C, passed through the fourth catalyst bed, then cooled and sent to a second absorption tower. The gas mixture goes to the first and second absorption tower, a packed tower where SO3 is absorbed into a counter-current flow of 98 99% sulfuric acid. The overall reaction can be described by the following equation, where sulfur trioxide reacts with the free water to produce sulfuric acid: SO3 + H2O â‚ ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  Ã¢â€š ¬Ã‚  H2SO4 à ¢Ã‹â€ Ã¢â‚¬  H = -200 kJ mol-1 The circulating sulfuric acid must be maintained at about 98% concentration and temperature is controlled in the desired rang of (70 °C_90 °C) to maximize the absorption efficiency. The acid strength is important because the vapor pressure of sulfur trioxide above sulfuric acid is at a minimum at an acid strength of 98% (see Figure (4.1. 3)). At higher concentrations the increased vapor pressure is caused by SO3 and at lower concentrations the water vapor pressure increases sharply and the resultant acid mist is not readily re-absorbed and escapes to the atmosphere. A stream of sulfuric acid is continuously bled off and cooled through a plate heat exchanger before being passed into the storage tanks. Figure (4.1.3): Relation Between Vapor Pressure and Concentration.7 Figure (4.1.4) : Flow Sheet CHAPTER FIVE ENERGY AND MASS BALANCE 5.1 MASS BALANCE *Drier: Components Amount % H20 1.27 1.3 O2 21.12 23 N2 69.4 75.7 Temperature 25C pressure 1 atm M1 M2 Components Amount % H2SO4 39.4 98 H2O 0.8 2 Temperature 150C pressure 1 atm M3 Components Amount % O2 21.12 23.3 N2 69.4 76.7 Temperature 25C pressure 1 atm M4 Components Amount % H2SO4 39.42 95 H2O 2.1 5 Temperature 150C pressure 1 atm *Burner: M3 Components Amount % O2 21.12 23.3 N2 69.4 76.7 Temperature 26C pressure 1 atm M5 Components Amount % S 3.76 100 Components Amount % SO2 28.16 29 O2 7.04 7 N2 69.4 64 Temperature 830C pressure 1 atm   M6 *Converter: M6 Components Amount % SO2 28.16 29 O2 7.04 7 N2 69.4 64 Temperature 400C pressure 1 atm M7 Components Amount % O2 2.11 2 N2 69.44 66 SO2 8.45 8 SO3 24.64 24 Temperature 450 pressure 1 atm M8 Components Amount % SO2 26.72 26 O2 1.69 1.6 N2 69.44 66.4 SO3 26.72 26 Temperature 450 pressure 1 atm M9 Components Amount % SO2 0.314 6 O2 0.0768 1.5 N2 3.47 66.5 SO3 1.36 26 Temperature 450 pressure 1 atm M10 Components Amount % SO2 0.314 6 O2 0.0768 1.5 N2 3.47 66.5 SO3 1.36 26 Temperature 450 pressure 1 atm M11 Components Amount % SO2 6.08 6 O2 1.54 6 N2 65.97 66.5 SO3 25.84 26 Temperature

Palestine By Joe Sacco; A Book Review Essay -- essays research papers

Joe Sacco’s graphic novel, Palestine, deals with the repercussions of the first intifada in Israel/Palestine/the Holy Land. The story follows the author through the many refugee camps and towns around Palestine as he tries to gather information, stories, and pictures to construct his graphic novel. While the book is enjoyable at a face level, there are many underlying themes conveyed throughout its illustrated pages and written text. The most obvious of the themes is that of violence, brutality, and torture. Tied into this also is the idea of injustice. Many of these themes are intertwined. Constantly the reader is berated with violent images, or descriptions of violence. These must be on nearly every second page of the novel. A good example of all these themes together is in the section called â€Å"Moderate Pressure: Part Two† This deals with a story of a man called Ghassan who was accused of an affiliation with an illegal group that could not be proven. Ghassan was forced to stand or sit in certain positions for hours on end, he was beaten, deprived of sleep, and restricted from medical attention that he needed. Continually he went to court, and the case was adjourned to later dates to try to confiscate some kind of evidence against him. There was no justice for Ghassan until after several days (approximately 14); he was released for lack of evidence. Ghassan suffers from violence (which is unjust), fro m brutality (one of the inspectors trying to induce a heart attack), and torture. Ghassan’s ordeal is illustrated in both written and pictorial form. Likewise to this, there are many other pictorial examples and textual examples from front to back of violence, brutality, injustice, and torture . There is also the theme of hypocrisy littered throughout the pages of Joe Sacco’s novel. This idea of hypocrisy is mainly centred on what the Israelis do to the Palestinians. In images the hypocrisy is apparent. Often there are pictures of the Palestinians on the same page, or on the second page but aligned with the Israelis. Often the Israeli side is shown as more optimistic, brighter, or livelier than those portraying the Palestinians. An excellent example of this is on page 260, where both Tel Aviv and Nablus are portrayed. In Tel Aviv, Sacco is reclined on a chair, with two attractive women, and it appears to be a sunny warm day, in Nablus, Sacco is with a crowd of... ...seem unnecessary and oppressive, but to certain Palestinians it is a matter of religious faith. Another example that shows this is when Sacco is in a car with Khaled . Kahled asks Sacco about things in the West that strike him as ‘bad’, but are quite normal to people from the West (i.e. Sex). These characteristics of evil also impact on an individual’s personal opinion of what is evil. In Palestine, the reader is exposed to various characters’ personal opinion of what evil or good is. An example of this is the figure of Suddam Hussein, to many people (Westerners, Israelis); Hussein is a very ‘evil’ figure. However, to some of the Palestinians represented, Hussein was a force of good, of liberation, the ‘final hope’. Evil in the novel is portrayed to the reader in many contexts that our society and cultural norms and values can understand. Brutal violence, deprivation, apartheid, and torture are all symbols of what we would see as evil. The book portrays the evil as seen by the Palestinians, many of these characteristics matching our own societal ideas of evil, so that the reader can comprehend. Bibliography Sacco, Joe. Palestine. Fantagraphics Books, Seattle: 2001.

Lord Of The Flies, Human Nature :: essays research papers

Human Nature   Ã‚  Ã‚  Ã‚  Ã‚  William Golding wrote two famous works, Lord of the Flies, and â€Å"Why Boys Become Vicious†. He was awarded the Pullet Surprise for Lord of the flies. They also made this book into two different movies. William Golding’s view of human nature is mankind is naturally evil, everyone is born that way. The book Lord of the Flies is a story about a group of young boys stranded on a disserted island. They have power struggles, and eventually break up into two different groups, the savages, and the normal kids. In William Golding’s other writing, â€Å"Why Boys Become Vicious†, he describes an event that took place in England. Two ten-year-old boys kidnapped two-year-old James Bulger, and beat him to death for no apparent reason. There are many people who agree with his ontological view but I am not one of them. William Golding believed that human nature is evil; however, I believe only some people are evil.   Ã‚  Ã‚  Ã‚  Ã‚  In the essay â€Å"Why Boys Become Vicious†, Golding proves what he wrote 40 years earlier about human nature. He tells about a real life example of humans at their worst. Two ten-year-old Liverpool boys have been charged with the death of two-year-old James Bulger. They kidnapped him from a shopping center with his mother not faraway. The two boys led him outside for a long walk until they came to a large group of boys, most around the age of 10. Then for no apparent reason they all started to beat little James. When they were through he was dead. Realizing what they had done, the boys moved his body to a rail road track, hoping a train would come so that no one could tell what they had done. The train didn’t come and the two boys were caught. In this essay Golding says â€Å"we are born with evil in us and cruelty is part of this† (â€Å"Why Boys Become Vicious†2). He thinks a likely cause of evil in boys is because of their parents. â€Å"If parents are absent, if fathers do not provide strength, and mothers do not provide love, then children will plumb the depths of their nature† (â€Å"Why Boys Become Vicious†3). William Golding proves his view by giving examples of horrible people like Hitler, Stalin, and Idi Amin.   Ã‚  Ã‚  Ã‚  Ã‚  In the book Lord of the Flies, William Golding tells a story about human nature at its worst.

Oedipus Tyrannus Essay

Oedipus Trynnus was Sophocles masterpiece and it occupies a key place in the Greek’s mythologies and probably the most famous. This Sophocles’s piece of work is also referred to as Oedipus Rex and was performed for the time in C429Bc. It was a play that was set in Thebes, a city that had been rocked by plague. In this mythology, the mother of Oedipus committed suicide by hanging herself while his real son Oedipus self exiled himself after he learned the truth that he had married his own biological mother. Oedipus had been abandoned by his father after the oracle told him that he would suffer in the hands of his own son and for this reason he ordered him to be killed. As he was ordered, shepherd refused to kill the child and gave it to another shepherd after he was unable to raise the child himself who then gave it to a childless king of Colinth, Polybus. He was raised and brought up in his courtyard until he was fully mature. All this time he never knew that those were not his real parents but through rumors, he learned that they were not his real parents and he felt like killing the king, Polybus. He decided to consult the Oracle over this issue but it declined to tell the truth although he later established the truth. The oracle seemed to ignore his question and instead told him that he would mate with his own mother and that he would shed the blood of his own sire with his own hands. (Sophocles, Meineck P, and Woodruff P. 2000) Oedipus pretended not to be hurt and continued to believe that Merope and Polybus were his real parents. Later he contemplated of leaving Corinth for Thebes to avoid the thoughts of killing them. On his way to Thebes on his chariot, he met a man whom they disagreed over who had the right to pass first. As the quarrel ensued, due to his arrogance Oedipus killed him but this was part of the prophecy that he would kill his parents using his own hands. He was not aware that that was his biological father. This action cannot be blamed on him that he killed his own father for it was a prophecy that he would shed the blood of his own sire and so he did. What should be known is that Oedipus was just fulfilling the prophecy of the oracle although he was doing this unconsciously. At time went on, Crossby H. (1860) he managed to solve a riddle that had left many baffled. This was known as Sphinx’s riddle and the riddle was, â€Å"what walks on four legs in the morning then at noon it uses two legs and in the evening on three legs? † Sphinx never imagined that anybody would unravel the mystery and so when it was done, she threw herself off the cliff side. Although again not aware of what Oedipus did, saving the world from the curse, he opened himself another door by being made the king and in addition he was given queen Jocasta to marry. This was her real mother but he was not aware. At this juncture oracle’s prophecy could be said to have materialized although none of the key players was aware even Oedipus himself despite the fact that he had been briefed by the Oracle. Immediately after he assumed the throne (Sophocles. 2006), he was promised a Prague by the gods for the murder of Laius. For this reason, he took it upon himself to look for the killer although he was not aware that he was the murderer. In aid of the search, a blind prophet, Tiresias was approached so that he would assist in bringing the killers to book. Soon, he was given a warning not to follow the matter and was blamed by the king of killing the man. In his retaliation he told the king that he was looking for himself something that made the king to look incredulous. The king in his reaction accused Teresias of being in conspiracy with Jocasta’s brother Creon to overthrow him. (Seagal C. 2000) It should be understood that the king had no other option apart from doing that because he was obliged to do so by the oracle although he was not aware that he was fulfilling the prophecy that had been made earlier to him that he would kill his own sire using his bare hands and the same happened when he killed the man over the chariot’s passage rights. Again as it had already prophesied that he would sleep with his own mother, the same happened when he married Jocasta, the queen who was given to him after she unraveled Sphinx’s riddle something that saved Thebes’s kingdom from gods’ curse. So he was just accomplishing what was predestined to happen in his life by the Oracle. He had no power to reverse this and so he was not to be blamed for his actions. If Oedipus knew that the man whom he quarreled with was his father and that the lady that was given to him as a reward was his biological mother, he wouldn’t have done what he did and so he was innocent and should not be blamed for his actions. (Crossby H. 1860) Oedipus came to learn the naked truth when king Polybus who raised Oedipus died and a messenger who was the only witness to the murder of Lais came to Thebes to convey the message of Polybus’ death (Wilson A. 994). He had run away from Thebes because he did not want to be the one that would reveal the secret. He kept his secret and the truth came to the right when the second messenger accompanied by a shepherd told him that his real parentage was unknown. While they were still seated there, her wife told him the truth something that hurt him very m uch. The truth was that he was the kid who was abandoned by Laius after he was told by the oracle that he would bring suffering to his own father. After this, his wife ran away and committed suicide by hanging herself and when the king learned of his death from his messenger he gouged his eyes out with the golden brooches that were on Jacasta’s dress. (Hunt A. J. 1937) This left him a confused man and that was why he blinded himself so that he would never meet his father in the after world. He even decided to exile himself leaving his children in the hands of Jocanta’s brother, care. At first he insisted to have the company of the children but Creon refused. In short though unaware, all his actions were predetermined and he was just doing what was in the Oracle’s design.

Le’ Chatelier’s Principle

Purpose: The purpose of this lab is to develop a deeper understanding of LeChatelier’s Principle by observing several systems at chemical equilibrium and interpreting the effects of varying concentrations and temperature. The principle states that if systems at equilibria are altered or disturbed in any form, the equilibria will shift to reduce the disturbing influence ( Catalyst, 186). In a 3 part experiment, we analyzed the outcome of changes in reactant and product concentrations, equilibrium involving sparingly soluble salts, and the effect of temperature on the equilibrium.In part 1 , we observed the shift in equilibria of two aqueous solutions of Copper and Ammonia then Nickel and Ammonia. In part 2, we focused on cobalt ions in the presence of chloride ions as well as the precipitation of silver nitrate and sodium carbonate. In the last part of the experiment we utilized a solution of Cobalt chloride and compared the color at room temperature and then again in a contain er of boiling water. Physical Data: No physical Data was applicable to the experiment. Chemical Equations: Part i: Changes in Reactant or Product Concentrations A. Copper and Nickel Ions [Cu(H2O)4]2+ (aq) + 4NH3(aq) [Cu(NH3)4]2+(aq) + 4H2O(l) blue dark blue †¢[Ni(H2O)6]2+(aq) + 6NH3(aq) [Ni(NH3)6]2+(aq) + 6H2O(l) green pale violet †¢H+(aq) + NH3(aq) NH4 +(aq) B. Cobalt Ions †¢[Co(H2O)6]2+(aq) + 4CL- (aq) [CoCl4]2-(aq) + 6H2O(l) Part ii: Equilibrium Involving Sparingly Soluble Salts †¢2AgNO3(aq) + Na2CO3(aq) Ag2CO3(s) + 2NaNO3(aq) †¢2Ag+(aq) + CO32-(aq) Ag2CO3(s) Net ionic equation ^ †¢2H+(aq) + CO32-(aq) H2CO3(aq); H2CO3(aq) > CO2(g) + H2O(l) Ag+(aq) + Cl-(aq)AgCl(s) †¢Ag+(aq) + 2NH3(aq) [Ag(NH3)2]+(aq) †¢I-(aq) + Ag+(aq) AgI(s) Safety †¢Safety goggles are required to be worn throughout entire duration of the lab experiment. †¢Wear gloves, as the chemicals may cause serious damage to the skin skin. †¢Be sure to clean mat erials with soap and water before beginning any procedures. †¢When disposing wastes, be sure to do so in the appropriate receptacle. †¢Use precaution when handling all chemicals, careful not to inhale anything. Experimental Procedure and Observations Part i: Changes in Reactant or Product ConcentrationsA. Copper and Nickel Ions Procedure Copper 1. Place 1 mL of 0. 1 M CuSO4 in a clean test tube. 2. Add 15 M NH3 drop wise until a color change occurs. 3. Mix the solution in the test tube as you add the NH3. 4. Add 1 M HCl drop wise while mixing the solution, until the color changes. Nickel 1. Place about 1 mL of 0. 1 M NiCl2 in a clean test tube. 2. Add 15 M NH3 drop wise until a color change occurs. 3. Mix the solution in the test tube as you add the NH3. 4. Add 1 M HCl drop wise while mixing the solution, until the color changes. Observations Copper . The liquid is light blue in color. 2. The solution turned to royal blue. 3. Solution begins to slowly change to a more tran sparent blue. 4. We added 56 drops, the top of the solution remained royal blue as the bottom turned completely clear and colorless. After shaking it, it turned completely light blue. Nickel 1. The liquid is light/clear green in color. 2. The solution turned from green to blue to a lavender complex. 3. The solution turned to a clear lavender color. 4. The solution reverted back to clear green. B. Cobalt Ions Procedure 1. Place 0. mL of 1 M CoCl2 in a test tube. 2. Add 12 M HCl to test tube until a change is noticeable. 3. Slowly add water to the test tube while mixing. Observations 1. Exactly 10 drops are placed in the tube. The liquid is pale pink in color. 2. The solution turned to dark blue. 3. The solution slowly turns to purple, as little particles form on the bottom. A pale pink color began to form at the top and the color consumed the entire solution. Part ii: Equilibrium Involving Sparingly Soluble Salts Procedure 1. Add 10 drops of 0. 01 M AgNO3 to 0. 5 mL of 0. 1 M of Na2C O3. . With caution, add 6 M HNO3 drop wise until a change occurs. 3. Add . 1 M of HCl drop wise until a change is observed. 4. Add 15 M NH3 drop wise until a change occurs. 5. Add 6 M HNO3 drop wise until there is evidence of a chemical change. 6. While mixing the solution, add 15 M NH3 drop wise. 7. Add 0. 1 M KI drop wise until there is evidence of a chemical reaction. Observations 1. The original Na2CO3 solution is clear in color. The addition of AgNO3 turns it cloudy almost immediately. A small amount of precipitate is also visible in the solution. 2.Exactly 4 drops of HNO3 are added and the color of the solution reverts back to clear. 3. 4 drops of HCl are also added and the solution once again turns back cloudy with visible precipitate. 4. 15 drops of NH3 are used and the solution becomes colorless with the precipitate dissolving. 5. The solution remains colorless and a small gas cloud forms over the solution. 6. The solution is still clear and the gas above is still visible. 7. The solution turns white/ creamy in color. There is visible precipitate and the gas above the liquid is no longer visible. Part iii. Effect of Temperature on EquilibriaProcedure 1. Using a 250 ml beaker, heat 75ml of water until it begins to boil. 2. Place 1 mL of 1. 0 M CoCl2 in a test tube and place the test into the boiling water (Careful not to spill). Observations 1. The water heats to a temperature of about 135 °C. 2. The color of the CoCl2 at 20 °C is red. After placing it in the boiling water it changes to a deep pink/magenta color. Data/ Results Part i: A Part i: B Part ii Part iii Calculations: No mathematical calculations were applicable to the experiment. Discussion: Beginning with the first experiment, which consisted of the Copper, Nickel, and Ammonia.In both reactions, the strength of the ammonia is stronger than that of the water, causing each of them to dissociate. Once Hydrochloric acid is added to left of the equation, the ammonia binds to hydrogen forming ammonium and driving the reaction back in the direction that it came from. The equilibrium is therefore established by the Nickel ion and Ammonia and shifted by the hydrochloric acid once the hydrogen reacts with ammonia in a common acid-base reaction. The ammonia-metal bond in each of the reactions causes a precipitate to form because of the hydroxide ions that are left after the donation of the hydrogen.Part B of the experiment consisted of the aqueous Cobalt and chloride ions. The addition of the hydrochloric acid, once again induces an immediate change in color. The equilibrium of the equation is disturbed because of the acid, which lead to the left shift in the equation. Increasing the amount of water allowed H2O to act as a base forming H3O, allowing the reaction to move back to the right. In the second portion of the lab, the combination of silver and sodium carbonate leads to the formation of a precipitate. This is accounted for based on the silver+carbonate complex.Adding h ydrochloric acid forms an unstable carbonic acid which will later dissociate into carbon dioxide and water. This also has the effect of dissolving the silver carbonate and shifting the equation back to the left. Further removal of the silver on the left forces the reaction to move in the direction of the loss. Silver ions react with ammonia that is added and added more acid to this caused ammonium to form. Ammonia is added once more to reestablish the equilibrium. The final add-on of potassium iodide once again disrupts the balance because the silver reacts the iodide causing the reaction to move left.By manipulating the temperature, we were able to deduce information about the final reaction involving cobalt chloride. Starting near room temperature at exactly 20 °C the cobalt chloride started at a light pink color. After placing the solution in a heated water bath of exactly 135 °C, the contents of the test tube turned dark pink. The reaction is therefore endothermic as the coo l CoCl2 absorbed heat from it’s water bath before making a chemical change, therefore the reaction shifts to the right to absorb the heat. Conclusion:Conducting the experiment gave us the opportunity to learn about the effects of varying concentration and temperature in a system, hence the objectives were met because in performing each section of the lab, we were able to apply LeChatelier’s principle. The methods applied greatly aided in our understanding of the material as we had to apply previous knowledge to understand the behavior of the chemicals. Many of the solutions that were added drop wise had to be done that way as to not add too much because too much of a substance could prevent the reversal properties of the reaction.

New Public Management Approach

The Concept of ‘New public management Approach’ New public management (NPM) denotes broadly the government policies, since the 1980s, which aimed to modernize and render more effective the public sector. The basic hypothesis holds that market oriented management of the public sector will lead to greater cost-efficiency for governments, without having negative side-effects on other objectives and considerations.The last two decades to 2006 have been associated with a fundamental shift in the principles of public sector management in all industrialized countries. This had, in turn, been a product of a general reinvention of the role of government, its agencies, the means by which services are delivered, and employment practices within public sector organizations. At its core, this has been associated with a move away from a traditional model of public administration towards variants of the ‘new public sector management’ model.The traditional model of public ad ministration, based on the doctrine of the separation of powers, was associated with the delegation of a specific set of functions to public administrators in the implementation of policy and the expenditure of public funds. A central principle associated with this model was the idea that public service employees were independent from the political process. Their role was encapsulated by the maxim of providing advice ‘without fear or favour’. This capacity for independent advice was assured through the idea of a career in the public service and explicit norms of behaviour and professional conduct.It has also been presumed that public service employees were less likely to be motivated by extrinsic rewards, more likely to identify with value of service to the public and the provision of public goods, and have a strong commitment to principles of justice, fairness and equity in discharging their duties. This traditional model of public administration was associated with an expansive view of the role of government, which prevailed throughout much of the twentieth century.This view produced a significant role for government in regulating economic and social relations, owning productive assets and producing goods and services, in a range of areas in the period until the mid to late 1970s. From that time, the role of government and public sector organisations came under sustained scrutiny, with the result that governments privatised production of many goods and services previously seen as the natural domain of government, such as essential services; withdrew from the direct control f production of goods and services funded by the public purse through corporatization and outsourcing; and encouraged the contestability of markets in which the government had previously been a monopoly producer. This general reorientation of the role of government has been associated with changes to internal organizational attributes and management practices within public sec tor organizations. This ‘new public management’ has shifted the focus from public service to service delivery.The principles associated with new public management have been informed by the idea that public service needs to be more responsive to both the preferences of beneficiaries, citizens who pay for service provision through tax, and politicians who represent the collective will and make policy choices. From this perspective, ministers are seen as analogous to customers, and citizens to consumers. New public management has been informed by economic doctrines that have advocated privatization, contestability in the delivery of public goods and services and, where possible, the provision of these goods and services through the private sector.For the core public service, this has also been associated with significant reforms to public employment systems and the norms of what constitutes professional public service. For Australian public service employees, this shift ha s involved the displacement of core legislative protections associated with independence by ‘value statements’ and ‘codes of ethical conduct’, along with protective legislation for whistleblowers. More generally, this shift has occurred within the context of a decentralization of managerial responsibilities for workforce planning and human resource management to individual departments and agencies.For middle managers, this has meant a significant increase in responsibility for both ensuring probity in managerial practice and dealing with the ethical issues and conflicts that arise in dealing with ministers and stakeholders, the responsible expenditure of public money and the fair and just delivery of services to the community. Developments Some modern authors define NPM as a combination of splitting large bureaucracies into smaller, more fragmented ones, competition between different public agencies, and between public agencies and private firms and incenti vization on more economic lines.Defined in this way, NPM has been a significant driver in public management policy around the world, from the early 1980s to at least the early 2000s. NPM, compared to other public management theories, is oriented towards outcomes and efficiency, through better management of public budget. It is considered to be achieved by applying competition, as it is known in the private sector, to organizations in the public sector, emphasizing economic and leadership principles. New public management addresses beneficiaries of public services much like customers, and conversely citizens as shareholders.In 2007, the European Commission produced a white book on governance issues whose objective was to propose a new kind of â€Å"relationship between the state and the citizens,† reform governance, improve public management and render decision-making â€Å"more flexible. † Criticism Some authors say NPM has peaked and is now in decline. Critics like Du nleavy proclaim that NPM is ‘dead' and argue that the cutting edge of change has moved on to digital era governance focusing on reintegrating concerns into government control, holistic (or joined-up) government and digitalization (exploiting the Web and digital storage and communication within government).In the UK and US NPM has been challenged since the turn of the century by a range of related critiques such as Third Way thinking (see Anthony Giddens) and particularly the rise of ideas associated with Public Value Theory (Mark Moore, Kennedy Business School, John Benington, Warwick Business School) which have re-asserted a focus on citizenship, networked governance and the role of public agencies in working with citizens to co-create public value, generate democratic authorisation, legitimacy and trust, and stress the domains within which public managers are working as complex adaptive systems with characteristics which are qualitatively different from simple market forms, or private sector business principles.In his book Bad Samaritans, economist Ha-Joon Chang claims that â€Å"increased NPM-inspired reforms have often increased, rather than reduced, corruption,† as a result of â€Å"more contacts [of state-sector functionaries] with the private sector, creating new opportunities for bribes† and future, direct or indirect, employment in the private sector. Chang claims that â€Å"corruption often exists because there are too many market forces; not too few. † Robert Nield, a retired Cambridge economics professor and a member of the 1968 Fulton civil service reform committee, has stated, in reference to civil sector reforms implemented by British PM Margaret Thatcher, a pioneer and strong proponent of NPM, â€Å"I cannot think of another instance where a modern democracy has systematically undone the system by which incorrupt public services were brought into being. â€Å"